However, there are still very few studies focused on Ga2O3 dielectrics prepared directly on III-V NWs since the typical thermal oxidizing method is challenging

to be executed on the small-diameter NWs, while the MS-275 atomic-layer-deposited (ALD) high-κ HfO2 and Al2O3 dielectrics often have significant interfacial defects when performed on NW materials [12]. In this case, it is necessary to explore other alternative dielectrics such as Ga2O3 achieved by other advanced techniques in order to tackle this issue for the versatile high-mobility III-V NW devices. Among many Ga2O3 phases, the monoclinic β-Ga2O3 is the most stable phase, being a promising gate dielectric alternative; nevertheless, it often requires synthesis at high temperatures to maintain its excellent crystallinity. For example, https://www.selleckchem.com/products/3-deazaneplanocin-a-dznep.html β-Ga2O3 NWs are usually prepared at above 1,000°C, employing Ga metal as the source in the chemical vapor deposition (CVD) [13], and sometimes even high-energy arc plasma is utilized when using GaN as the starting material [14]. As most III-V NWs are synthesized at a moderate temperature in the range 400°C to 600°C via vapor-liquid-solid (VLS) and/or vapor-solid-solid (VSS) mechanisms [15–18], a compatible low-temperature β-Ga2O3 growth technique is therefore essential to grow dielectrics laterally

on III-V NWs while not degrading the III-V NW materials with high vapor pressures. Recently, we have adopted various III-V material Hydroxychloroquine datasheet powders as precursor sources for the NW growth by CVD, such as obtaining GaAs, InP, GaSb, etc. at a temperature of 500°C to 600°C [19–21]. Here, MLN2238 cost in this report, we perform detailed studies on the synthesis behaviors and fundamental physical properties of β-Ga2O3 NWs at this moderate growth temperature in a similar CVD growth system. It is revealed that highly crystalline and insulating β-Ga2O3 NWs are successfully grown on the amorphous SiO2 substrate, which provides a

preliminary understanding of the β-Ga2O3 NWs attained by the solid-source CVD method, and further enables us to manipulate the process parameters to achieve high-quality gate dielectrics laterally grown on III-V semiconductor NWs for the coaxially gated NW device structures [22]. Methods Synthesis of Ga2O3 NWs The Ga2O3 NWs were synthesized in a dual-zone horizontal tube furnace, where the upstream zone was used for evaporating the solid source and the downstream zone for the NW growth, as reported previously [15]. At first, 50-nm Au colloids (standard deviation of approximately 5 nm, NanoSeedz, Hong Kong) were drop-casted on SiO2/Si substrates (50-nm thermally grown oxide) to serve as the catalyst, which were then placed in the middle of the downstream zone with a tilt angle of approximately 20°. The solid source, GaAs powders (approximately 1.